MAKE A MEME View Large Image Flippin-Lodge-angle-2D.png Diagram of the Flippin-Lodge angle of nucleophilic attack on a carbonyl compound The greater the angle ψ the more the nucleophile approaches from the side of the substituent R ² For example it had been calculated ...
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Keywords: Flippin-Lodge-angle-2D.png Diagram of the Flippin-Lodge angle of nucleophilic attack on a carbonyl compound The greater the angle ψ the more the nucleophile approaches from the side of the substituent R ² For example it had been calculated that hydride H<sup> </sup> attacks pivalaldehyde tBuCHO with a Flippin-Lodge angle of 7° This avoids the steric clash of H<sup> </sup> and tBu Based on a diagram on p 160 of cite book Fleming Ian Molecular Orbitals and Organic Chemical Reactions Student 978-0-470-74659-2 John Wiley Sons Ltd 2009 Own 2012-01-20 Ben Mills Benjah-bmm27 Images by Ben Mills Nucleophilic addition reactions
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